In a large nonstick skillet, brown pork chops on both sides in oil.
Remove and keep warm.
In the same pan, combine brown sugar, vinegar, soy sauce, molasses, and orange peel until blended.
Return meat to pan; cover and simmer for 15 minutes or until tender.
Remove chops and keep warm.
Combine cornstarch and water until smooth; stir into pan juices.
Bring to a boil, cook, and stir for 2 minutes or until thickened.
Add orange segments and cook for 1 minute.
Serve over rice.